11110 固態熱力學

# Core Courses # Graduate Program
11 Lectures / 105 Sections / 20h 24m 26s
Lecture 1：Outline of the course
Section 1
02:13
Lecture 2：Introduction
Section 1
07:21
Section 2
13:34
Lecture 3：The First Law of Thermodynamics
Section 1
07:48
Section 2
10:08
Section 3
05:27
Section 4
12:44
Section 5
09:20
Section 6
09:44
Section 7
08:38
Section 8
14:20
Section 9
11:47
Lecture 4：The Second and Third Law of Thermodynamics
Section 1
13:45
Section 2
12:02
Section 3
13:57
Section 4
10:32
Section 5
11:50
Section 6
10:31
Section 7
13:16
Section 8
04:24
Section 9
11:57
Section 10
07:31
Section 11
09:39
Section 12
10:56
Section 13
15:48
Lecture 5：Relations among Thermodynamic Quantities
Section 1
16:44
Section 2
14:36
Section 3
11:54
Section 4
14:27
Section 5
10:48
Section 6
16:03
Lecture 6：Thermodynamics of Phase Transformations
Section 1
11:09
Section 2
10:43
Section 3
15:13
Section 4
09:40
Section 5
11:21
Section 6
11:50
Section 7
10:48
Section 8
10:44
Section 9
15:26
Section 10
08:24
Section 11
14:30
Section 12
09:28
Lecture 7：Thermodynamics of Solid Solutions
Section 1
14:00
Section 2
12:20
Section 3
09:00
Section 4
11:36
Section 5
12:42
Section 6
15:40
Section 7
15:18
Section 8
11:15
Section 9
15:44
Section 10
09:13
Section 11
05:05
Section 12
10:40
Section 13
11:15
Section 14
10:53
Section 15
00:00
Section 16
14:35
Section 17
10:58
Lecture 8：Free Energy of Binary Systems
Section 1
14:13
Section 2
13:00
Section 3
08:47
Section 4
12:34
Section 5
14:36
Section 6
11:55
Section 7
11:45
Section 8
11:52
Section 9
13:04
Section 10
10:42
Section 11
11:08
Section 12
14:08
Section 13
08:45
Section 14
12:25
Section 15
16:31
Section 16
15:59
Lecture 9：Phase Diagrams
Section 1
11:52
Section 2
12:03
Section 3
13:55
Section 4
08:42
Section 5
10:41
Section 6
14:18
Section 7
12:13
Section 8
16:06
Section 9
17:17
Section 10
12:08
Section 11
16:16
Section 12
13:16
Section 13
16:39
Lecture 10：Thermodynamics of Surfaces
Section 1
09:36
Section 2
08:47
Section 3
08:17
Section 4
15:18
Section 5
13:15
Section 6
13:02
Section 7
08:39
Section 8
13:14
Lecture 11：Thermodynamics of Nanomaterials
Section 1
05:52
Section 2
14:24
Section 3
11:33
Section 4
11:08
Section 5
11:51
Section 6
06:51
Section 7
10:25
Section 8
12:10
Introduction
Duration｜ 20h 24m 26s
Total Lectures｜ 11 Lectures 105 Sections

The videos will become accessible as the on-site classes progress.

Course Description

This is an advanced course of thermodynamics for graduate students in the Department of Materials Science and Engineering. Students from other disciplines in science and engineering are also welcome to take. The course will start from review of the three laws of thermodynamics and then move to more insight of entropy and free energies. The calculation and application of Gibbs free energy in solid solutions and alloy systems will be emphasized, which will then be correlated with the construction of phase diagrams. The thermodynamics involved in surface energy, nanomaterials, and electrochemistry will be elaborated. Students will be asked to participate in classroom discussion. Teaching materials may come from the OCW or MOOCs on the web. The lecture will be given in English.

Course keywords:

internal energy, enthalpy, Helmholtz free energy, Gibbs free energy, entropy, heat capacity, solid solution, phase diagram, surface energy, nanomaterials

指定用書(Text Books)

    1. Robert DeHoff, "Thermodynamics in Materials Science," 2nd ed., Taylor & Francis, 2006.
    2. Ira N. Levine, Physical Chemistry, 6 ed., McGraw-Hill, 2009.

參考書籍(References)

    1.  “Introduction to the Thermodynamics of Materials,” 6th ed., 2018, David R. Gaskell and David E. Laughlin, Taylor & Francis.
    2. "Thermodynamics of Solids," 2nd ed., 1972, Richard A. Swalin, John Wiley & Sons, Inc.
    3. “Phase Transformations in metals and Alloys,” 3rd ed., by D.A. Porter, K.E. Easterling and M.Y. Sherif, CRC Press, 2009.

教學方式(Teaching Method)

    1. Lecture in English
    2. Video of previous lectures

教學進度(Syllabus)

    1. Introduction
    2. The First Law of Thermodynamics
    3. The Second and Third Laws of Thermodynamics
    4. Thermodynamics of Phase Transformations
    5. Thermodynamic Properties of Solid Solutions
    6. Free energy of Binary Systems
    7. Phase Diagrams
    8. Thermodynamics of Surfaces
    9. Thermodynamic Properties of Nanomaterials
    10. Electrochemical Thermodynamics
Lectures
Lecture 1：Outline of the course
Section 1 - Outline of the course
02:13
Lecture 2：Introduction
Section 1 - Three laws of thermodynamics
07:21
Section 2 - Terminologies and unit conversion
13:34
Lecture 3：The First Law of Thermodynamics
Section 1 - Definition of the system pressure
07:48
Section 2 - Heat capacity, thermal expansion coefficient, and compressibility
10:08
Section 3 - Difference between CP and CV
05:27
Section 4 - Internal energies of ideal gases
12:44
Section 5 - Enthalpy and heat capacities
09:20
Section 6 - Isothermal and adiabatic expansion and compression of ideal gases
09:44
Section 7 - The first law of thermodynamics
08:38
Section 8 - Heat capacities of elemental solids
14:20
Section 9 - Expansion and compression of a gas
11:47
Lecture 4：The Second and Third Law of Thermodynamics
Section 1 - The second law of thermodynamics, entropy, and Carnot cycle
13:45
Section 2 - Entropy changes of reversible and irreversible ideal gas expansion
12:02
Section 3 - Entropy changes of an ideal gas by a 4-step irreversible expansion
13:57
Section 4 - Entropy change of water by a one-step heating
10:32
Section 5 - Entropy changes of water by a 2-step or 4-step heating
11:50
Section 6 - Combination of the first and second laws, Maxwell relations
10:31
Section 7 - Helmholtz and Gibbs free energies, total △S and system △G
13:16
Section 8 - Getting H and S from G
04:24
Section 9 - Making use of Maxwell relations
11:57
Section 10 - Dependence of enthalpy on temperature and pressure
07:31
Section 11 - Dependence of entropy on temperature and pressure
09:39
Section 12 - Configurational entropy, the third law of thermodynamics
10:56
Section 13 - Molecular interpretation of entropy
15:48
Lecture 5：Relations among Thermodynamic Quantities
Section 1 - Definition and application of the standard state
16:44
Section 2 - Standard state values of elements and substances from the table
14:36
Section 3 - Tables A1, A2 and A3 from Gaskell's "Thermodynamics of Materials"
11:54
Section 4 - Calculation of enthalpy and entropy changes from heat capacities
14:27
Section 5 - Equilibrium constant and free energy change
10:48
Section 6 - Chemical potential
16:03
Lecture 6：Thermodynamics of Phase Transformations
Section 1 - Free energy curves for one-component systems
11:09
Section 2 - Classification of phase transitions
10:43
Section 3 - Order-disorder and superconductive-normal phase transitions
15:13
Section 4 - Phase diagram of H2O
09:40
Section 5 - Free energy curves of H2O at different pressures
11:21
Section 6 - Free energy curves of H2O at different temperatures
11:50
Section 7 - Effect of external pressure on the transition temperature
10:48
Section 8 - Clausius-Clapeyron equation for vapor pressure
10:44
Section 9 - Effect of external pressure on the vapor pressure
15:26
Section 10 - ΔH and ΔS for metastable phase transition of H2O
08:24
Section 11 - Metastable phase transition of Sn, Richard's and Trouton's rules
14:30
Section 12 - Transformation of graphite to diamond
09:28
Lecture 7：Thermodynamics of Solid Solutions
Section 1 - Ideal gas mixtures
14:00
Section 2 - Fugacity of real gases
12:20
Section 3 - Fugacities of some real gases
09:00
Section 4 - Fugacity of condensed phases
11:36
Section 5 - Definition of activity
12:42
Section 6 - Activity as a measure of escaping tendency
15:40
Section 7 - Behavior of ideal solutions
15:18
Section 8 - Sieverts' law
11:15
Section 9 - Regular solutions
15:44
Section 10 - Mixing entropy and configurational entropy
09:13
Section 11 - Non-regular solutions
05:05
Section 12 - Activity coefficient and Henry's law
10:40
Section 13 - Quasichemical model
11:15
Section 14 - Ω and non-ideality
10:53
Section 15 - Bonding preference and atomic configuration
Section 16 - Electromotive force and Gibbs free energy
14:35
Section 17 - Gas electrodes and gas fugacity
10:58
Lecture 8：Free Energy of Binary Systems
Section 1 - How to get chemical potential and activity from the free energy curve
14:13
Section 2 - Free energy curves vs Ω
13:00
Section 3 - Activity vs Ω
08:47
Section 4 - Activity vs composition
12:34
Section 5 - Miscibility gap vs Ω
14:36
Section 6 - Isomorphous system vs Ω
11:55
Section 7 - Activity vs standard state
11:45
Section 8 - Negative mixing enthalpies and phase diagrams
11:52
Section 9 - Positive mixing enthalpies and phase diagrams
13:04
Section 10 - Free energy curves of eutectic systems
10:42
Section 11 - Effect of supercooling on the shift of eutectic phase diagram
11:08
Section 12 - Shift of eutectic phase diagram by Gibbs-Thomson equation
14:08
Section 13 - Free energy curve and chemical spinodal
08:45
Section 14 - Spinodal decomposition vs nucleation and growth
12:25
Section 15 - Gradient energy and coherent strain energy
16:31
Section 16 - Schematic phase diagram for miscibility gaps and spinodals
15:59
Lecture 9：Phase Diagrams
Section 1 - Gibbs phase rule
11:52
Section 2 - One-component phase diagrams
12:03
Section 3 - Isomorphous system
13:55
Section 4 - Hume-Rothery rules
08:42
Section 5 - Eutectic system
10:41
Section 6 - Features of eutectic systems
14:18
Section 7 - Peritectic, eutectoid, and monotectic transformations
12:13
Section 8 - Intermetallic compounds and intermediate phases
16:06
Section 9 - Order-disorder phase transformation, Fe-Fe3C phase diagram
17:17
Section 10 - Three-component phase diagrams
12:08
Section 11 - Ternary isotherms
16:16
Section 12 - Fe-Cr-Ni system
13:16
Section 13 - Y2O3-BaO-CuO system
16:39
Lecture 10：Thermodynamics of Surfaces
Section 1 - Interfacial free energy
09:36
Section 2 - Composition variation across the interface
08:47
Section 3 - Surface concentration
08:17
Section 4 - Surface free energy vs surface energy
15:18
Section 5 - Gibbs adsorption equation, values of surface energy
13:15
Section 6 - Chemical potential of curved interfaces
13:02
Section 7 - Surface energy vs surface tension
08:39
Section 8 - Anisotropy of surface energy, Wulff plot
13:14
Lecture 11：Thermodynamics of Nanomaterials
Section 1 - Fractions of atoms on the surface
05:52
Section 2 - Melting point and cohesive energy of surface atoms
14:24
Section 3 - Melting point and Gibbs-Thomson equation
11:33
Section 4 - Nanosize effect on modification of phase diagrams
11:08
Section 5 - Solid state amorphization of layered structure
11:51
Section 6 - Mechanical alloying
06:51
Section 7 - Atomic layer deposition
10:25
Section 8 - Enhanced solubility by nanolamination
12:10
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Prof. Tsong-Pyng Perng
Prof. Tsong-Pyng Perng

Dept.  Materials Science and Engineering

Research Field

Processing, Characterization, and Applications of Nanomaterials

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